Chemistry 105/106

1:0 Introduction
1:1 Quick History of Chemistry
1:2 The Scientific Method
1:3 The Composition of Matter
1:4 International System of Units (SI)
1:5 Factor-Label Method
1:6 Errors
1:7 Significant Figures
1:8 SF and Mathematical Operations
1:9 Propagated Errors
2:0 Atoms and Molecules
2:1 Atoms and Molecules
2:2 Moles
2:3 Atomic and Molecular Weights
2:4 Derivation of Molecular Formulas
2:5 Percent Composition
2:6 Chemical Equations
2:7 Stoichiometry
2:8 Limiting Reagents
3:0 Solution Stoichiometry
3:1 Molarity
3:2 Dilution
3:3 Solution Stoichiometry
4:0 Gases
4:1 The Early Laws
4:2 Ideal Gas Law
4:3 Density of Gases
4:4 Gas Stoichiometry
4:5 Partial Pressures
4:6 Kinetic Molecular Theory of Gases
4:7 Molecular Velocities
4:8 Graham
4:9 Real Gases
5:0 Thermochemistry
5:1 Energy
5:2 Specific Heats
5:3 Calorimetry
5:4 Enthalpy
5:5 Properties of Enthalpy Change
5:6 Hess
5:7 Standard Enthalpies of Formation
6:0 Atomic Structure and Quantum Mechanics
6:1 Early Characterization of the Atom
6:2 Symbols for Atomic Structure
6:3 Isotopes
6:4 Ions
6:5 From Classical to Quantum Physics
6:6 The Photoelectric Effect
6:7 Bohr
6:8 Wave Mechanics
6:9 Heisenberg
6:10 The Development of Quantum Mechanics
6:11 The Particle in a Box
7:0 Quantum Numbers and Periodicity
7:1 Quantum Numbers for the Hydrogen Atom
7:2 Multi-Electron Atoms
7:3 Energy Levels
7:4 The Aufbau Principle
7:5 The Periodic Table
7:6 Electronic Configuration of Ions
7:7 Magnetic Properties
7:8 Atomic Radii
7:9 lonization Energies
7:10 Electron Affinity
7:11 Expected Ions from Periodic Table
8:0 Bonding I
8:1 Chemical Bonding
8:2 Ionic Bonding
8:3 Covalent Bonding
8:4 The Hydrogen Molecule
8:5 Electronegativity
8:6 Ionic vs. Covalent
8:7 Covalency
8:8 Sigma (a) and Pi (TT) Bonds
8:9 Drawing Lewis Structures
8:10 Three Dimensionality of Lewis Structures
8:11 Expected Geometries With Lone Pairs
8:12 Polarity vs. Geometry
9:0 Bonding II: Advanced Concepts
9:1 Hybrid Orbitals
9:2 Molecular Orbital (MO) Theory
9:3 Interaction of Two s Atomic Orbitals
9:4 Interaction of Two p Atomic Orbitals
9:5 Heteronuclear Diatomic Molecules
10:0 Condensed Phases
10:1 Intermolecular Forces, IMF
10:2 Solids
10:3 Metals and Closest Packing
10:4 Bonding in Metals
10:5 Ionic Crystals
10:6 Liquids
10:7 Vapor Pressure
10:8 Temperature Dependence of VP
10:9 Heating Curves
10:10 Phase Diagrams
11:0 Solutions and Their Properties
11:1 Classification of Solutions
11:2 Henry
11:3 Concentration Units
11:4 Net Ionic Equations
11:5 Raoult
11:6 Raoult
11:7 Binary Solutions - Real Solutions
11:8 Solid Solutions
11:9 Colligative Properties
11:10 Osmotic Pressure
12:0 Chemical Kinetics
12:1 Introduction
12:2 Nature of the Reactants
12:3 Concentration of Reacting Species
12:4 T e Inital Rate Method
12:5 Solutions to Differential Rate Equations
12:6 Graphical Method
12:7 Effect of Temperature on Rate
12:8 Collision Theory
12:9 Temperature Dependence on Rate Constant
12:10 Transition State Theory and Catalysis
12:11 Reaction Mechanisms
12:12 Steady-State Approximation
12:13 Enzyme Kinetics
13:0 Organic Chemistry
13:1 Introduction
13:2 Alkanes
13:3 IUPAC Nomenclature
13:4 Alkyl Halides
13:5 Alkenes
13:6 Stereoisomers, Part I
13:7 Reactivity of Alkenes
13:8 Alkynes
13:9 Aromatics
13:10 Cycloalkanes
13:11 Functional Groups
13:12 Stereoisomers, Part II: Chirality
13:13 Nucleophilic Substitution Reactions
13:14 Second Order Mechanism (SN2)
13:15 First Order Mechanism (SN1)
14:0 Spectroscopy
14:1 Experimental Determination of Structure
14:2 Mass Spectroscopy
14:3 Infrared Spectroscopy
14:4 General Diagram of an IR Spectrometer
14:5 Infrared Spectra Analysis
14:6 Degrees of Unsaturation in Organic Compounds
14:7 Nuclear Magnetic Resonance Spectroscopy
14:8 Spin-Spin Coupling
14:9 Drawing NMR Spectra
14:10 Analysis of an NMR Spectrum
14:11 Additive Effect
15:0 Organic Reactions Revisited
15:1 Introduction
15:2 Addition to Alkenes
15:3 Free Radical Substitution in Alkanes or Alkyl Groups
15:4 Nucleophilic Substitution Reactions
16:0 Thermodynamics
16:1 Introduction
16:2 The First Law of Thermodynamics
16:3 Physical and Chemical Transformations
16:4 Expansion Work
16:5 Energy and Enthalpy
16:6 Heat Capacities
16:7 Chemical Transformations
16:8 Entropy
16:9 Entropy Changes for Other Physical Processes
16:10 Second Law of Thermodynamics
16:11 Entropy Changes in Chemical Processes
16:12 Calculation of Absolute Entropies
16:13 Dependence of Free Energy on Pressure
16:14 Equilibrium
17:0 Chemical Equilibrium
17:1 Introduction
17:2 Properties of the Equilibrium Constant
17:3 Le Chatelier's Principle
17:4 Chemical Equilibrium Problems
17:5 Strategy for Solving Chemical Equilibria Problems
18:0 Acids and Bases
18:1 Bronsted Lowry Acid/Base Concept
18:2 Acid Strength and Molecular Geometry
18:3 Ka's and Kb's
18:4 Autoionization of Water
18:5 pH, a Logarithmic Scale
18:6 Hydrolysis
18:7 Common Ion Effect
18:8 Buffers
18:9 Conjugate Acid/Base Pairs - II
18:10 Acid Base Titrations
18:11 Polyprotic Acids
18:12 Lewis Acids and Bases
18:13 Lewis Bases versus Bronsted Bases
19:0 Other Aqueous Equilibria: Ksp
19:1 Slightly Soluble Salts
19:2 Common Ion Effect in Solubility Equilibria
19:3 Precipitation
20:0 Electrochemistry
20:1 Redox Reactions
20:2 Oxidation States
20:3 Balancing Redox: Ion-Electron Method
20:4 Electrochemistry: An Introduction
20:5 Units
20:6 Galvanic Cells
20:7 Conventional Notation
20:8 Electromotive Force (EMF)
20:9 Half-Cell Potentials
20:10 EMF As a Function of Concentration
20:11 Calculation of Equilibrium Constants
20:12 Electrolysis
20:13 Faraday's Laws
21:0 Appendices
21:1 Thermodynamic Parameters
21:2 Equilibrium Constants
21:3 Ksp Values for Some Common Ionic Solids at 25C.
21:4 Standard Reduction Potentials